
The tunable elasticity and porosity of colloidal gels lead to some interesting applications, among them tissue scaffolding and drug delivery. Conventionally, colloidal particles interact and assemble under entropic and electrostatic forces to form predictable structures. But greater control can be achieved from an approach developed by Paul Clegg, Michael Cates, and their collaborators at the University of Edinburgh in the UK. The researchers disperse silica particles in the single-phase region of two partially miscible solvents—water and the organic base 2,6-lutidine. When the solution is heated above a critical temperature, the solvents separate and the particles become trapped at the liquid–liquid interfaces. The bulky particle domains then jam together and arrest the solvent separation, forming a two-phase network the researchers call a bijel. But cool the solution and remix the solvents too soon and the distinct structure disappears, as shown in movie 1 and the two left images in which the colloids appear green, the water black, and the lutidine red. Now the researchers have discovered an approach to stabilize the bijel structure. When the phase-separated solution is allowed to sit for at least 24 hours before it is cooled, the bijel surprisingly keeps its shape, as shown in the two right images and movie 2. From Monte Carlo simulations, the researchers deduce how the resulting network of colloidal monolayers, or monogel, stays intact: the particles become compressed by capillary forces, remain attracted by van der Waals forces, and are kept from collapsing into each other by repulsive electrostatic forces. (E. Sanz et al., Phys. Rev. Lett., in press.) —Jermey N. A. Matthews




With their ability to manipulate microliter to nanoliter volumes of liquids, microfluidic devices have found increasing application in a variety of fields, from ink-jet technology to proteomics and DNA analysis. Most current microfluidic devices are made from glass or polymers, and advances in design and fabrication have opened the realm of three-dimensional, complex flow paths.
At the very moment a droplet of water breaks away from a dripping faucet, a singularity is formed. The dynamics leading up to the singularity are governed by the competition between the water’s inertia and its surface tension. (Water’s viscosity is low enough that it does not play a role.) In the reverse setup—an air bubble breaking away from an underwater nozzle—the pinch-off process is driven instead by the difference in pressure between the air and the water. As a result, the bubble and droplet systems differ both in the shapes formed and in the dependence on time. Now,
When you pull hard enough on two objects that are stuck together by an adhesive, they become unstuck. How that happens depends on the properties of the adhesive. A viscoelastic liquid deforms into thin fibrils as air penetrates the bulk of the adhesive, whereas an elastic solid can debond cleanly from the surface of one of the objects as air enters at the interface. Now, Julia Nase,